UKL met her husband while they were both Fulbright scholars bound for Paris in 1953. "a young historian named Charles LeGuin, a tall, handsome Georgian with a flattop who was studying at Emory University in Atlanta." - Julie Phillips [also biographer of Alice Sheldon aka James Tiptree Jr], in an untitled biographical article in 80!: Memories & Reflections on Ursula K. Le Guin, ed. Karen Joy Fowler and Debbie Notkin (Seattle: Aqueduct Press, 2010), p. 171. Possibly the fact that they were in Paris when they got married has confused people. It was the French registrar who was responsible for insisting on the space between the "Le" and the "Guin". Later: "In the summer of 1954, the Le Guins returned to the United States ... took the train to Macon, Georgia, Charles's hometown. Charles got a job teaching history at Mercer University in Macon, and Ursula was hired as an instructor in French." - Phillips, op. cit, p. 173-4.

Also, there's his edition of his grandmother's diaries.